Contenido

• Introduction
• Fundamental Concepts
  • The Cluster Expansion
  • The Cluster Operator
  • Other Cluster-Based Wavefunctions
  • Size-Extensivity and Size-Consistency
• Formal Coupled-Cluster Theory
  • Construction of the General CC Equations
  • Truncation of the CC Equations
  • A Variational Coupled-Cluster Theory?
  • The Hausdorff Expansion
• Practical Coupled-Cluster Theory
  • Normal-Ordered Operators
  • Wick's Theorem
  • The Normal-Ordered Hamiltonian
  • Algebraic Construction of the CCD Equations
  • Diagrammatic Construction of the CCD Equations
• Second Quantization
  • Creation and Annihilation Operators
  • Second-Quantized Representation of Operators
  • Usefulness of Second-Quantized Operators
• Relationship to Configuration Interaction
• Referencias
• Índice
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