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Graphene nanoislands  


Graphene nanoislands are nanometric sized regions of graphene. They have been observed on Ru surfaces. Also chemist are able to synthetize a variety of flat graphene-based molecules  known as nanographenes.   We have studied graphene nanoislands with zigzag edges. The simplest islands with that shape are triangles and hexagons.  We have found that triangles have a net magnetic moment, localized in the edges, that scales with the size of the island. Hexagons always have total zero magnetic moment but sufficiently large islands display spin polarized edges with opposite polarization (see figure). The minimal size for the appearence of polarization in the edge of hexagon islands is 2nm.  The fact that carbon-based nanostructures can be magnetic is very surprising. To know more:

Our paper:
"Magnetism in Graphene Nanoislands", J. Fernández-Rossier and J. J. Palacios,
Phys. Rev. Let. 99, 177204 (2007)

Online article for non-experts in Nanotech web:
"Graphene nanoislands go magnetic" (link)

Experimental work:
J. Wu, W. Pisula, K. Mullen, "Graphene Molecules as Potential Material for Electronics", Chem. Rev., 2007, 107, 718-747.  (link to web of professor Wu)

Amadeo Vázquez de Parga et al., "Periodically rippled graphene: growth and spatially resolved electronic structure"  http://arxiv.org/abs/0709.0360


triangular islandshexagon